• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    An advantageous anodic structure, particularly useful for cathodic protection of metal structures having a large linear extension, is made of an insulated power cable having a suitable terminal at least at one end for the electrical connection to the positive pole of the electrical source and of a series of anodic segments distributed over the lenght of the power cable, coaxial with the cable itself and electrically connected through a leak-proof connection with the conductive core of the insulated power cable without interruption of the core continuity.
    公开号:SU1175361A3
    申请号:SU833537162
    申请日:1983-01-17
    公开日:1985-08-23
    发明作者:де Нора Оронцио；Бианчи Джузеппе
    申请人:Оронцио Де Нора Импианти Элеттрохимици,С.А.(Фирма)；
    IPC主号:
    专利说明:


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    The invention relates to a cathodic protection device with a large linear extent, which are used in the field of cathodic protection by a superimposed current system.
    The purpose of the invention is to increase the effectiveness of protection by stabilizing the transient resistance of the anodode. . FIG. 1 shows a device layout.
    in FIG. 2 - schematically two anodes; in fig. 3 is a section. A-A in FIG. 2j on fayag. 4 - stretched sheet, used as an anode element, axonometric; in fig. 5 is a cross section of bb-bna of fig. four. .
    The device contains an insulated power cable 1 with a core of intertwined copper or aluminum wires coated with insulation from an elastomeric material, for example, synthetic or natural rubber, polyvinyl chloride, polyethylene, fluorinated vinyl polymer, etc.
    able to withstand corrosive environment.
    To increase the tensile strength of the cable, the latter may have a core of steel wires or an entire core of steel wires.
    One end of the cable is provided with a lug 2 for connection to the positive pole of the power source. The other end of the cable is provided with a titanium or plastic cap 3, both, sealing and sealing the corrosive core from contact with the environment. It is advisable to make a cap with a hook or ring for fastening the end of the anode or the ballast suspension. At this end of the cable, you can attach a waterproof, detachable contact connection that allows a series of anode structures to be joined in series, doubling or losing the length of the anode structure, if necessary.
    A series of anodes 4 is coaxially mounted on the cable, the number of which and the distance between them is determined by specific conditions.
    The number of anodes and their distribution along the cable should ensure the uniformity of current in the protected surface. The distribution of the anodes along the cable is determined mainly by the shape of the electric field, which
    must be created between the anode structure and the surface to be protected.
    An advantage of the invention is its flexibility and ability to locate it at any desired length. . .
    Each anode (Fig. 2) contains a porous permeable body 5, made of a stretched sheet or
    or more racks 6, which in turn are welded to the clutch 7.
    The anodes are made of valve metal, for example, titanium or tantalum or their alloys.
    The cross section of the main body 5 may have a circular, square, polygonal, star-shaped, etc. the form, and the body itself must be porous, permeable or made-. n1m from strips of metal mesh welded to one or more racks 6,
    The mesh or mesh segments forming the permeable body 5 are covered with a layer of electrically conductive and anodic-resistant material, for example, a platinum group metal or its oxide, or another electrically conductive metal oxide, such as spinel delfossite, perovskite, bronze
    etc. Particularly effective is a thermally applied coating.
    by the method of a layer of a mixture of ruthenium oxides and titanium, in a ratio of 20 RU and 80 Ti to 60 RU and 40% Ti.
    In the main structure of ruthenium oxides, and titanium, small amounts of oxides of other metals may be present.
    Each anode can be manufactured in advance, and then put on the power cable 1, the housing 5 can be welded to the posts 6 after the coupling 7 is fixed on the power supply cable.
    I.
    For electrical connection
    The electrically conductive core of the insulated cable 1 and the anode 4, first, in the area corresponding to the central zone of the coupling 7, the plastic insulation 8 of the cable is removed. After that, the coupling 7 is crimped at the sections with the removal of the insulation of the power cable 1 and at the neighboring isolated areas in order to ensure the tight protection of the electrical connection. metal network welded to one 3. The compression of the metal sleeve 7 is carried out using a special tool for radial cold reduction. Protective covers are made of a plastic pipe that shrinks when heated and made from, for example, fluorinated copolymers of ethylene and propylene. These covers are put on the points of the joint of the coupling 7 with the cable and are fixed by heating the hot air from the blower to improve the protection of the connection from the release medium. To fabricate the anode body (Figs. 4 and 5), an expanded sheet of valve metashta, such as titanium, coated with a layer of electrically conductive non-passivable material resistant to anode conditions is used, and this coating is applied to all surfaces as a whole. The anodes of the present invention have several advantages compared with conventional plate or rod anodes. When used in the earth, the drilling fluid and the filling solution easily penetrate into the porous and permeable structure of the anode, thereby creating a large contact surface, which is three-dimensional and is the sum of all contact surfaces that are oriented in different ways in space. As a result, the surface area increases dramatically and even when the soil dries out or gas is released. At the anode it still remains large enough. The gas that is located at the anode finds its way in the anode grid. The problems associated with the fact that the medium cannot easily pass to the surfaces of the rod or plate anode can be easily solved by using the scientific research institute of anodes. Comparative tests of cathodic protection carried out at industrial installations convincingly show the advantages of porous anodes over solid ones. Due to the fact that the soil easily penetrates into the porous anode, the contact resistance decreases by about 15% at the beginning of operation, and after three months of operation, the contact resistance of the porous anode is 25-30% lower than 614 contact resistance of the solid anode. Example. One proposed anodic structure consists of ten anodes or distributors (Fig. 2-5). The anodes are made of stretched (fluffed) titanium sheet 1.5 mm thick, rolled into cylinders 50 mm in diameter (outer) and 1500 mm long. These cylinders of stretched sheet are coated with a mixture of ruthenium oxides and titanium in the ratio of 1: 1 for metal. Expanded sheet cylinders are welded to titanium struts, which in turn are welded to a titanium pipe with an internal diameter of 10 mm, worn on a power supply cable and cold-crimped on the cable to provide a seal for the electrical connection, and for some time one to create an electrical connection. A rubber insulated power cable with an external diameter of about 8 mm and a copper flexible core with a cross section of about 10 mm. The intervals between the anodes are equal in length to the cable and are about 2 m. One end of the cable is embedded in a titanium cap that is cold-crimped on the cable to protect the cable from the environment. The cap is equipped with a titanium hook. The other end of the cable is divided into a copper lug suitable for connection to a power source. Such an anodic structure is immersed in a well with a diameter of about 12.5 cm and a depth of 40 m, drilled into the ground with an average resistivity of 1000 ohm cm. After lowering the cable, the well is filled with a bentonite solution. This anode is used to protect about 15 km of a gas pipeline with a diameter of 500 mm, made of steel pipe, coated with synthetic rubber - on the basis of dense polyethylene, laid to a depth of about 2 meters in the soil. The measured resistance when the anode structure was turned on with respect to ground was 0.7 Ohm, and the current flowing out of the anode at a voltage of about 7.5 V is 8A. Resistance measured after
    is three months of operation, ls 0.82 ohms.
    For comparison, an anodic structure similar to the one proposed is used, but the anode elements are made of solid titanium tubes;
    and covering which correspond to the proposed dp mesh anodes.
    The resistance of this structure to the ground when turned on was 0.8 Ohm, and after three months of operation it rose to 1.4 Ohm.
    f-j
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    Fmg.1
    FIG. 2 Fig5 fAgM
    5
    权利要求:
    Claims (2)
    [1]
    ($ 7) 1. PROTECTION DEVICE
    FROM CORROSION, containing an insulated cable connected to a power source, a number of metal anodes distributed along the length of the cable, fixed coaxially with it and electrically connected with an electrically conductive core, characterized in that, in order to increase the efficiency of protection by stabilizing the transition resistance of the anode-earth For anode, the anodes are made in the form of a porous permeable housing made of valve metal coated with a layer of non-resistant metal, the housing being connected to an electrical conductive cable by a sleeve made of valve metal.
    [2]
    2. The device pop. 1, characterized in that the housing is made of rolled titanium sheet.
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    同族专利:
    公开号 | 公开日
    DK156836B|1989-10-09|
    JPS58181876A|1983-10-24|
    NO159944C|1989-02-22|
    EP0084875B1|1986-11-05|
    DK22083A|1983-07-22|
    US4519886A|1985-05-28|
    NZ203058A|1986-01-24|
    EP0084875A3|1983-08-10|
    ES8402883A1|1984-03-01|
    US4452683A|1984-06-05|
    IT8219208D0|1982-01-21|
    NO830098L|1983-07-22|
    DK156836C|1990-03-05|
    DK22083D0|1983-01-20|
    NO159944B|1988-11-14|
    BR8300230A|1983-10-18|
    UA5968A1|1994-12-29|
    MX152676A|1985-10-07|
    EP0084875A2|1983-08-03|
    AU553651B2|1986-07-24|
    DE3367418D1|1986-12-11|
    AR232007A1|1985-04-30|
    AU9178282A|1983-07-28|
    IT1150124B|1986-12-10|
    ES519147A0|1984-03-01|
    AT23368T|1986-11-15|
    JPS6315994B2|1988-04-07|
    JPS60150573A|1985-08-08|
    CA1215937A|1986-12-30|
    引用文献:
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    RU2544330C2|2009-06-15|2015-03-20|Гэрет ГЛАСС|Anti-corrosion protection of steel in concrete|US2876190A|1955-04-18|1959-03-03|Union Carbide Corp|Duct anode|
    US2851413A|1957-07-02|1958-09-09|Jr Harry W Hosford|Anode assembly for cathodic protection system|
    DE1110983B|1958-11-26|1961-07-13|Siemens Ag|Electrode, especially for electrical corrosion protection of metal parts|
    US3022242A|1959-01-23|1962-02-20|Engelhard Ind Inc|Anode for cathodic protection systems|
    FR1256548A|1960-02-05|1961-03-24|Contre La Corrosion Soc Et|Flexible anode device for cathodic protection of metal structures|
    US3098027A|1960-12-09|1963-07-16|Flower Archibald Thomas|Anode connector|
    BE632783A|1962-05-26|
    US3527685A|1968-08-26|1970-09-08|Engelhard Min & Chem|Anode for cathodic protection of tubular members|
    US3616418A|1969-12-04|1971-10-26|Engelhard Min & Chem|Anode assembly for cathodic protection systems|
    US3981790A|1973-06-11|1976-09-21|Diamond Shamrock Corporation|Dimensionally stable anode and method and apparatus for forming the same|
    DE2645414C2|1976-10-08|1986-08-28|Hoechst Ag, 6230 Frankfurt|Titanium anodes for the electrolytic production of manganese dioxide, as well as a process for the production of these anodes|
    GB1568885A|1977-05-09|1980-06-11|Imi Marston Ltd|Impressed current corrosion-protection anode|
    JPS5838512B2|1978-02-21|1983-08-23|Nakagawa Boshoku Kogyo Kk|
    US4170532A|1978-04-11|1979-10-09|C. E. Equipment, Inc.|Deep well platinized anode carrier for cathodic protection system|
    US4267029A|1980-01-07|1981-05-12|Pennwalt Corporation|Anode for high resistivity cathodic protection systems|IT1163581B|1983-06-23|1987-04-08|Oronzio De Nora Sa|PROCEDURE FOR CARRYING OUT THE ELECTRICAL CONNECTION OF NON-CORRODIBLE ANODES TO THE CORRODIBLE SOUL OF THE POWER CORD|
    IT1170053B|1983-12-23|1987-06-03|Oronzio De Nora Sa|PRE-PACKED DISPERSER ANODE WITH BACKFILL IN FLEXIBLE STRUCTURE FOR CATHODIC PROTECTION WITH IMPRESSED CURRENTS|
    IT1196187B|1984-07-12|1988-11-10|Oronzio De Nora Sa|ELECTRODICAL CONTROL STRUCTURE FOR CATHODIC PROTECTION|
    IT1200414B|1985-03-13|1989-01-18|Oronzio De Nora Sa|DEVICE AND RELATED METHOD FOR THE COLLECTION OF CHEMICAL, ELECTROCHEMICAL AND MECHANICAL PARAMETERS FOR THE DESIGN AND / OR OPERATION OF CATHODIC PROTECTION SYSTEMS|
    US5451307A|1985-05-07|1995-09-19|Eltech Systems Corporation|Expanded metal mesh and anode structure|
    US5423961A|1985-05-07|1995-06-13|Eltech Systems Corporation|Cathodic protection system for a steel-reinforced concrete structure|
    DE3666232D1|1985-05-07|1989-11-16|Eltech Systems Corp|Cathodic protection system for a steel-reinforced concrete structure and method of installation|
    US4708888A|1985-05-07|1987-11-24|Eltech Systems Corporation|Coating metal mesh|
    US5098543A|1985-05-07|1992-03-24|Bennett John E|Cathodic protection system for a steel-reinforced concrete structure|
    US5421968A|1985-05-07|1995-06-06|Eltech Systems Corporation|Cathodic protection system for a steel-reinforced concrete structure|
    IT1206747B|1986-03-10|1989-05-03|Oronzio De Nora Sa|IMPRESSED CURRENT CATHODIC PROTECTION SYSTEM OF OIL PLATFORMS AT SEA.|
    FR2613541B1|1987-04-06|1990-04-06|Labinal|PROCESS FOR PRODUCING LEAD TERMINALS OR THE LIKE ON ALUMINUM CABLES|
    US5176807A|1989-02-28|1993-01-05|The United States Of America As Represented By The Secretary Of The Army|Expandable coil cathodic protection anode|
    DE4224539C1|1992-07-27|1993-12-16|Heraeus Elektrochemie|Anode cathodic corrosion protection - has ring packing and press sleeve around the cable connecting and current supply bolt|
    AU5257996A|1995-03-24|1996-10-16|Alltrista Corporation|Jacketed sacrificial anode cathodic protection system|
    JP4530296B2|2008-04-09|2010-08-25|Ｎｅｃアクセステクニカ株式会社|Variable angle structure|
    US7998631B2|2009-03-10|2011-08-16|GM Global Technology Operations LLC|Method to reduce/eliminate shunt current corrosion of wet end plate in PEM fuel cells|
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    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    IT19208/82A|IT1150124B|1982-01-21|1982-01-21|ANODIC STRUCTURE FOR CATHODIC PROTECTION|
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